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薛王欣  张婧  楚亮 《化学通报》2022,85(10):1154-1160,1223
钙钛矿太阳电池是一项颠覆性的光伏技术,具有能量转化效率高、生产成本低、制备工艺简单等优势。当前,钙钛矿太阳能电池的认证效率已达25.7%,但其面临着严重的商业化瓶颈,如稳定性差、模组效率相对低、铅毒性等,且这些问题相互关联。本文简述了钙钛矿太阳能电池的工作原理和器件结构,并归纳总结了在解决钙钛矿太阳能电池稳定性、封装和模组化等商业化瓶颈问题方面的主要研究进展。最后,本文提出了钙钛矿光伏商业化进程中值得关注的解决措施。  相似文献   
64.
Acetic acid, which is formed during degradation of the most frequently used photovoltaic (PV) encapsulant ethylene vinyl acetate (EVA), is linked to several PV module failure mechanisms like corrosion of interconnectors, cells or potential induced degradation (PID). An evaluation of a new measurement technique and data analysis for acetic acid permeation through photovoltaic backsheet films is described. The influence of the layer composition of the multilayer backsheets on the acetic acid permeation rates (AATR) was determined by investigating the permeation properties of the individual layers as well as the whole polymeric multilayer composites. Various polymeric backsheet types based on PET-core layers showing a very high barrier for acetic acid permeation were compared to fully polyamide material stacks which allow for a much higher transmission of acetic acid through the backsheet out of the module. Incorporated Al-layers were found to not affect the AATRs of PET based backsheets.  相似文献   
65.
We present various approaches to J. Herzog's theory of generalized local cohomology and explore its main aspects, e.g., (non-)vanishing results as well as a general local duality theorem which extends, to a much broader class of rings, previous results by Herzog-Zamani and Suzuki. As an application, we establish a prescribed upper bound for the projective dimension of a module satisfying suitable cohomological conditions, and we derive some freeness criteria and questions of Auslander-Reiten type. Along the way, we prove a new characterization of Cohen-Macaulay modules which truly relies on generalized local cohomology, and in addition we introduce and study a generalization of the notion of canonical module.  相似文献   
66.
The present paper, though inspired by the use of tensor hierarchies in theoretical physics, establishes their mathematical credentials, especially as genetically related to Lie algebra crossed modules. Gauging procedures in supergravity rely on a pairing – the embedding tensor – between a Leibniz algebra and a Lie algebra. Two such algebras, together with their embedding tensor, form a triple called a Lie-Leibniz triple, of which Lie algebra crossed modules are particular cases. This paper is devoted to showing that any Lie-Leibniz triple induces a differential graded Lie algebra – its associated tensor hierarchy – whose restriction to the category of Lie algebra crossed modules is the canonical assignment associating to any Lie algebra crossed module its corresponding unique 2-term differential graded Lie algebra. This shows that Lie-Leibniz triples form natural generalizations of Lie algebra crossed modules and that their associated tensor hierarchies can be considered as some kind of ‘lie-ization’ of the former. We deem the present construction of such tensor hierarchies clearer and more straightforward than previous derivations. We stress that such a construction suggests the existence of further well-defined Leibniz gauge theories.  相似文献   
67.
超声相控阵技术是目前聚乙烯管道热熔接头内部缺陷检测的一种主流方法。提出了基于注意力机制的改进Faster-RCNN目标检测网络用于超声相控阵D扫图聚乙烯管接头内部缺陷检测。针对聚乙烯管道热熔接头内部超声相控阵D扫图小缺陷较多、特征信息容易丢失的问题,将残差网络(ResNet50)与特征金字塔网络(FPN)相结合作为骨干网络,并引入卷积注意力模块(CBAM)自适应细化特征。将SSD网络框架和Faster-RCNN网络框架用于模型训练和测试,使用VGG16、ResNet50、ResNet50+FPN、ACBM+ResNet50+FPN作为骨干网络依次对超声相控阵聚乙烯管道热熔对接接头内部缺陷样本进行训练对比。结果表明,改进的Faster-RCNN网络模型在聚乙烯管接头内部缺陷检测和分类方面有明显改进,对小缺陷的检测性能有了显著的提高。  相似文献   
68.
We present analytical formulae for the first and second derivatives of the Helmholtz free energy of non-relativistic ideal Fermi gas. Important thermodynamic quantities such as heat capacity, sound velocity, heat capacity ratio, and others are explicitly expressed through the derivatives. We demonstrate correct ideal Boltzmann gas and low-temperature Fermi gas asymptotes and derive corrections to thermodynamic functions for these limiting cases. Numerical computations of thermodynamic properties of ideal Fermi gas can be accurately performed using the developed freely available Python module ifg .  相似文献   
69.
The (2+1)-dimensional Boiti–Leon–Manna–Pempinelli (BLMP) equation is an important integrable model. In this paper, we obtain the breather molecule, the breather-soliton molecule and some localized interaction solutions to the BLMP equation. In particular, by employing a compound method consisting of the velocity resonance, partial module resonance and degeneration of the breather techniques, we derive some interesting hybrid solutions mixed by a breather-soliton molecule/breather molecule and a lump, as well as a bell-shaped soliton and lump. Due to the lack of the long wave limit, it is the first time using the compound degeneration method to construct the hybrid solutions involving a lump. The dynamical behaviors and mathematical features of the solutions are analyzed theoretically and graphically. The method introduced can be effectively used to study the wave solutions of other nonlinear partial differential equations.  相似文献   
70.
应用于LED灯具散热的平板热管传热特性   总被引:3,自引:0,他引:3  
平板热管作为一种新型的热管技术,具有高热导率,良好的均温性等优点,成为解决大功率LED散热问题很有前途的技术之一。本文通过实验与数值模拟相结合的方法,研究了平板热管散热模组的传热性能,探讨了热源布置方式(集中式布置与分散式布置)的影响,为LED芯片的布置提供理论指导。结果表明:该平板热管散热模组的散热效果良好,能有效解决LED灯的散热问题。  相似文献   
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